Role of boson-fermion statistics on the Raman spectra of Br2(X) in helium clusters.
نویسندگان
چکیده
The role played by the bosonic or fermionic character of He atoms surrounding a Br2(X) molecule is analyzed through vibrotational Raman spectra simulations. Quantum chemistry-type calculations reveal the spin multiplicity to be chiefly responsible for the drastic difference observed by Grebenev et al. [Science 279, 2083 (1998)]] in the rotational structure of molecules embedded in helium droplets.
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ورودعنوان ژورنال:
- Physical review letters
دوره 93 5 شماره
صفحات -
تاریخ انتشار 2004